Thanks so much for the response. Thanks to your feedback, I think I have a solution. I created a new Access Control profile and:
* Blocked all P2P traffic
* Blacklisted 192.168.1.0/24
* Added the device I want to block to the profile
I then joined the device to the Guest network and it cannot:
* Get to the pcWrt login page
* Browse any shares
* Get to other device LAN network pages
I think that will do it! Thank you. Apologies for not mentioning that I know the device name I want to block.